An accurate measurement of energy shifts and relative intensities of hypers
atellite and satellite transitions in cobalt have been made. The use of rad
ioactive Ni-59, which decays mostly by the nuclear K-electron capture to co
balt and the low-probability processes of ejection of the other K-electron
allowed the observation of decays among very pure double inner-shell-hole s
tates. The measurements were made using a pair of high-purity germanium det
ectors in conjunction with a fast-slow coincidence system and a 128 x 512 x
512-channel three-parameter pulse-height analyzer. The results for the hyp
ersatellite shifts are Delta (K alpha (h)) = 274.9 +/- 1.6 eV and Delta (K
beta (h)) = 354.5 +/- 4.6 eV, and for the satellite shifts Delta (K alpha (
s) L-1) = 25.1 +/- 1.4 eV, Delta (K beta (s) L-1) = 39.1 +/- 4.8 eV and Del
ta (K alpha (s) M-1) = 8.8 +/- 4.2 eV. The results for the intensity ratios
are I(K beta (h))/K alpha (h)) = 0.119 +/- 0.006, I(K beta (s) L-1)/I(K al
pha (s) L-1) = 0.114 +/- 0.007, and I(K beta (s) M-1)/I(K alpha (s) M-1 = 0
.092 +/- 0.023. Present results and the available results of earlier work a
re compared. (C) 2001 Published by Elsevier Science B.V.