Stopping cross sections for swift heavy ions are commonly parameterized in
terms of a velocity-dependent effective charge defined with reference to pr
oton or helium stopping. This assumes projectile screening by core electron
s to be a dominating factor governing the velocity dependence of the stoppi
ng cross section. In this note Mle demonstrate? on the basis of improved th
eoretical estimates of stopping cross sections, that projectile screening o
nly affects the quantitative details of the velocity dependence of the effe
ctive charge while the general behavior reflects the transition from the Bo
rn to the classical regime. This is consistent with the experience that eff
ective charges derived from measured stopping cross sections show dependenc
ies on projectile and target atomic number which differ distinctly from tho
se of the equilibrium projectile charge. It follows that there is no theore
tical basis for the effective-charge concept as it is commonly used in heav
y-ion stopping. (C) 2001 Elsevier Science B.V. All rights reserved.