Spin order due to orbital fluctuations: Cubic vanadates

Citation
G. Khaliullin et al., Spin order due to orbital fluctuations: Cubic vanadates, PHYS REV L, 86(17), 2001, pp. 3879-3882
Citations number
29
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
86
Issue
17
Year of publication
2001
Pages
3879 - 3882
Database
ISI
SICI code
0031-9007(20010423)86:17<3879:SODTOF>2.0.ZU;2-Y
Abstract
We investigate the highly frustrated spin and orbital superexchange interac tions in cubic vanadates. The fluctuations of t(2g) orbitals trigger a nove l mechanism of ferromagnetic interactions between spins S = 1 of V3+ ions a long one of the cubic directions which operates already in the absence of H und's rule exchange J(H), and leads to the C-type antiferromagnetic phase i n LaVO3. The Jahn-Teller effect can stabilize the orbital ordering and the G-type antiferromagnetic phase at low temperatures, but large entropy due t o orbital fluctuations favors again the C phase at higher temperatures, as observed in YVO3.