Photochemical phosphorylation of (alkylthio)chloroacetylenes with phosphorus trichloride

Citation
Sg. D'Yachkova et al., Photochemical phosphorylation of (alkylthio)chloroacetylenes with phosphorus trichloride, RUSS J G CH, 70(10), 2000, pp. 1530-1532
Citations number
16
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
10
Year of publication
2000
Pages
1530 - 1532
Database
ISI
SICI code
1070-3632(200010)70:10<1530:PPO(WP>2.0.ZU;2-I
Abstract
Phosphorus trichloride regioselectively adds to (alkylthio)chloroacetylenes under UV irradiation to give a mixture of the E and Z isomers of [2-(alkyl thio)-1,2- dichlorovinyl]dichlorophosphines in high yield.