Hydrosilylation of 2-phenylpropene with dichloromethylsilane and transformations of the resulting adduct

Citation
Og. Yarosh et al., Hydrosilylation of 2-phenylpropene with dichloromethylsilane and transformations of the resulting adduct, RUSS J G CH, 70(10), 2000, pp. 1555-1556
Citations number
4
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
10
Year of publication
2000
Pages
1555 - 1556
Database
ISI
SICI code
1070-3632(200010)70:10<1555:HO2WDA>2.0.ZU;2-5
Abstract
2-Phenylpropene was hydrosilylated with dichloromethylsilane in the presenc e of H2PtCl6 to synthesize dichloromethyl(2-phenylpropyl)silane. The latter was reacted with methanol in the presence of carbamide to obtain dimethoxy methyl(2-phenylpropyl)silane whose reaction with methylmagnesium iodide gav e methoxydimethyl(2-phenylpropyl)silane Treatment of the latter with 40% HF gave fluorodimethyl(2-phenylpropy)silane which was reacted with BrMgC drop CH to obtain dimethylethynyl(2-phenylpropyl)silane.