Autooxidation of cyclic esters of boric acids

Authors
Kuznetsov, VV Mazepa, AV Spirikhin, LV
Citation
Vv. Kuznetsov et al., Autooxidation of cyclic esters of boric acids, RUSS J G CH, 70(10), 2000, pp. 1576-1580
Citations number
22
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
10
Year of publication
2000
Pages
1576 - 1580
Database
ISI
SICI code
1070-3632(200010)70:10<1576:AOCEOB>2.0.ZU;2-Z
Abstract
H-1 NMR and IR spectroscopy and mass spectrometry were used to show that th e major products of the autooxidation of substituted 1,3,2-dioxaborinanes a nd 1,3,2-dioxaborolanes upon prolonged handling are the corresponding 2,2'- oxybis(1,3,2-dioxaborinanes) and a,2'-oxybis(1,3,2-dioxaborolanes). A proba ble mechanism of this transformation is discussed.