Polarized absorption spectra experiments were carried out to investigate th
e structural symmetries of color centers of PbWO4 crystals. It was found th
at the intensity of the electrical vector E perpendicular to c of the radia
tion-induced 320 nm absorption band equals that of the E parallel to c, ind
icating the non-dichroic character of the band. Based on the analysis of th
e energy band structure and the crystal structure of PbWO4, the origin of t
he radiation-induced 320 nm absorption band was ascribed to the V-F(0) di-h
ole center. (C) 2001 Published by Elsevier Science Ltd.