Mh. Kuok et al., Hypersonic frequency softening and relaxation in relaxor ferroelectric 0.8Pb(Zn1/3Nb2/3)O-3-0.2PbTiO(3), SOL ST COMM, 118(4), 2001, pp. 169-172
Brillouin scattering from relaxer ferroelectric 0.8Pb(Zn1/3Nb2/3)O-3-0.2PbT
iO(3) has been measured in the 300-723 K temperature range. A sharp ferroel
ectric phase transition from cubic to tetragonal symmetry, associated with
a phonon frequency dip and a Landau-Khalatnikov-like damping maximum, has b
een observed near 528 K. Evidence for a relaxation mode in the form of a br
oad Rayleigh wing, whose frequency is strongly temperature dependent above
528 K, is found. The relaxation time and frequency are evaluated based on t
he tunneling model and a modified-superparaelectric model, respectively. (C
) 2001 Elsevier Science Ltd. All rights reserved.