The crystal structure of Pb2Fe(CN)(6) and Sn2Fe(CN)(6) has been first deter
mined and refined using the Rietveld method with combined Cu-K alpha (1) X-
ray and constant-wavelength neutron powder diffraction data in space group
P-3 (147, Z = 1). The unit cell constants are a = 7.1346(1) and 7.1805(1) A
ngstrom, c = 5.4531(2) and 5.3639(1) Angstrom, respectively. The compounds
are layered, groups of three nearest [Fe(CN)(6)](4-)-complexes are joined t
o layers by means of Pb or Sn atoms. The same Pb or Sn atoms (c.n. = 3+3) j
oint three nearest complexes from the next layer. The jointing goes through
'nitrogen-lead(tin)-nitrogen' bonds. (C) 2001 Editions scientifiques et me
dicales Elsevier SAS. All rights reserved.