The high temperature oxidation of Si(001) produces a 13 Angstrom thick oxid
e consisting of four or five layers with uniformly graded composition, rang
ing from monovalent at the Si interface to quadrivalent at the surface. Onc
e nucleated, the oxide layer rapidly reaches full thickness and then grows
laterally, A few atomic layers of the underlying elemental Si are measurabl
y perturbed by the sub-oxide overlayer. (C) 2001 Published by Elsevier Scie
nce B.V.