Citation
F. Le Bideau et al., New and efficient synthesis of CpRe(CO)(3) substituted steroids, TETRAHEDRON, 57(18), 2001, pp. 3939-3944
Citations number
13
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020
→ ACNP
Volume
57
Issue
18
Year of publication
2001
Pages
3939 - 3944
Database
ISI
SICI code
0040-4020(20010430)57:18<3939:NAESOC>2.0.ZU;2-N
Abstract
Fulvenes generated from steroids have been efficiently engaged in a process
implying nucleophilic or basic attack followed by a transmetallation react
ion in the presence of BrRe(CO)(5) to afford the corresponding CpRe(CO)(3)
substituted compounds. This new strategy is of relevant interest for the sy
nthesis of new potential radiopharmaceuticals. (C) 2001 Elsevier Science Lt
d. AU rights reserved.