The Bergman reaction as a synthetic tool: advantages and restrictions

Citation
Dm. Bowles et al., The Bergman reaction as a synthetic tool: advantages and restrictions, TETRAHEDRON, 57(17), 2001, pp. 3753-3760
Citations number
16
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
57
Issue
17
Year of publication
2001
Pages
3753 - 3760
Database
ISI
SICI code
0040-4020(20010423)57:17<3753:TBRAAS>2.0.ZU;2-I
Abstract
The Bergman cycloaromatization reaction efficiently converts easily prepare d acyclic enediynes into aromatic rings. In order to prepare larger, functi onalized fused aromatic systems using this reaction, a thorough understandi ng of how functionalization affects cycloaromatization is necessary. We pre sent here our studies on the influence of substituents at three different f unctionalization sites on cycloaromatization, and how these functional grou ps can be tailored to prepare more complex systems. (C) 2001 Elsevier Scien ce Ltd. AH rights reserved.