Catalytic oxidation of methane to formaldehyde. Computer modeling for chemical engineering evaluation

Citation
L. Botar et al., Catalytic oxidation of methane to formaldehyde. Computer modeling for chemical engineering evaluation, ACH-MODEL C, 137(5-6), 2000, pp. 711-724
Citations number
10
Categorie Soggetti
Chemistry
Journal title
ACH-MODELS IN CHEMISTRY
ISSN journal
12178969 → ACNP
Volume
137
Issue
5-6
Year of publication
2000
Pages
711 - 724
Database
ISI
SICI code
1217-8969(2000)137:5-6<711:COOMTF>2.0.ZU;2-R
Abstract
Evaluation of process variables of catalytic oxidation of methane into form aldehyde obtained in continuous flow, continuous flow recycle and flow recy cle batch laboratory reactors based on theoretical and mathematical statist ical considerations is carried out. A set of two linearly independent react ions is defined and introduced as multistep overall reaction mechanism in t he conservation equations. Arrhenius parameters are evaluated by statistica l methods. Conversion of methane, selectivity, yield and space-time yield a re computed in function of catalyst concentration, reaction temperature and residence time. Based on their analysis viable process parameters and the type of continuous flow recycle reactor are suggested for chemical engineer ing purposes.