Can HSO4- and SO42- ions adsorbed on an electrode be distinguished on the basis of measurement of thermodynamic nature?

Authors
Lang, GG Aramata, A Horanyi, G
Citation
Gg. Lang et al., Can HSO4- and SO42- ions adsorbed on an electrode be distinguished on the basis of measurement of thermodynamic nature?, ACH-MODEL C, 137(5-6), 2000, pp. 817-844
Citations number
20
Categorie Soggetti
Chemistry
Journal title
ACH-MODELS IN CHEMISTRY
ISSN journal
12178969 → ACNP
Volume
137
Issue
5-6
Year of publication
2000
Pages
817 - 844
Database
ISI
SICI code
1217-8969(2000)137:5-6<817:CHASIA>2.0.ZU;2-Q
Abstract
On the basis of a strict thermodynamic approach, the contradictions between views on the nature of adsorbed species in HSO4-/SO42- system are once mor e discussed. It is demonstrated that adsorbed HSO4- and SO42- species canno t be distinguished only on the basis of measurements of thermodynamic natur e by using a method proposed earlier.