We analyze ISO archive data of the nearby bright emission-line star 51 Oph,
previously classified as a proto-planetary system similar to P Pie. The in
frared spectrum reveals the presence of gas-phase emission bands of hot (si
milar to 850 K) CO, CO2, H2O and NO. In addition to this, partially crystal
line silicate dust is present. The solid-state bands and the energy distrib
ution are indicative of dust that has: formed recently, rather than of debr
is dust. The presence of hot molecular gas and the composition of the circu
mstellar dust are highly unusual for a young star and are reminiscent of wh
at is found around evolved (AGB) stars, although we exclude the possibility
of 51 Oph belonging to this group. We suggest several explanations for the
nature of 51 Oph, including a recent episode of mass loss from a Be star,
and the recent destruction of a planet-sized body around a young star.