Performance of Pt/Al-SBA-15 catalysts in hydroisomerization of n-dodecane

Citation
C. Nie et al., Performance of Pt/Al-SBA-15 catalysts in hydroisomerization of n-dodecane, CATAL LETT, 71(1-2), 2001, pp. 117-125
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
CATALYSIS LETTERS
ISSN journal
1011372X → ACNP
Volume
71
Issue
1-2
Year of publication
2001
Pages
117 - 125
Database
ISI
SICI code
1011-372X(2001)71:1-2<117:POPCIH>2.0.ZU;2-#
Abstract
A series of Al-SBA-15 materials with different Si/Al ratios have been prepa red via a post-alumination procedure. The results show that Al species can be introduced into the SBA-15 framework. Only the medium acid sites can be observed on the Al-SBA-15 samples, and the number of acid sites decreases w ith the increase of the Si/Al ratio. The hydroisomerization activities of n -dodecane over 1% Pt/Al-SBA-15-n catalysts increase with the number of acid sites, and the largest isomers yield reaches to 51%. It suggests that the Al-SBA-15 material is a suitable acid component for bifunctional catalysts for hydroisomerization of long chain n-paraffins.