Electron attachment in HBr and HCl

Citation
T. Speck et al., Electron attachment in HBr and HCl, J CHEM PHYS, 114(19), 2001, pp. 8303-8309
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
114
Issue
19
Year of publication
2001
Pages
8303 - 8309
Database
ISI
SICI code
0021-9606(20010515)114:19<8303:EAIHAH>2.0.ZU;2-C
Abstract
Studies of electron attachment in HBr and HCl gases at low temperatures hav e indicated that attachment to clusters of these gases can become efficient even though attachment to the monomers is endothermic and exhibits very lo w attachment rates. A complementary measurement of the reaction of OH radic als with HBr has enabled us to establish a lower limit for the rate of elec tron attachment to HBr clusters of approximately 10(-8) cm(3) s(-1). (C) 20 01 American Institute of Physics.