Bipolar membrane electroacidification (BMEA) was used to produce high-purit
y bovine milk casein isolates. However, a deposit suggested to be a mix of
calcium and magnesium salts was observed on the cation-exchange membrane (C
EM) side in contact with the base. The aim of the present study was to comp
lete the identification of the deposit formed on CMX membrane during bipola
r membrane electroacidification of skim milk, and to characterize its physi
cal structure at the interfaces of CEM. The results showed that a calcium d
eposit was found on both sides of the membranes as well as inside the membr
ane. This fouling was identified as calcium carbonate, but was likely a mix
between calcium carbonate and hydroxyde. (C) 2001 Academic Press.