Synthesis of poly(styrene sulfonate) brushes

Dense poly(styrene sulfonate sodium salt) brushes were prepared on silicone wafers using a two-step procedure: polystyrene (PS chains, terminated by a reactive trichlorosilane group, were first covalently grafted, and then th e PS brush was converted to a poly(styrene sulfonate) brush by a soft sulfo nation reaction. Ellipsometry and infrared spectroscopy in ATR were used to characterize the samples and to optimize the procedure: in particular, the sulfonation was shown to be homogeneous along the chain backbone and the n eutralization complete. In some cases, the polymer layer revealed to be qui te fragile: the chains were pulled nut of the brush. A consolidation treatm ent which consisted in grafting oligomers inbetween the Long PS chains sign ificantly increased the robustness of the layer. This might be relevant for industrial applications.