A C-3-symmetric chiral hexadentate podand ligand based on a tris(pyrazolyl)borate core

Authors
Motson, GR Mamula, O Jeffery, JC McCleverty, JA Ward, MD von Zelewsky, A
Citation
Gr. Motson et al., A C-3-symmetric chiral hexadentate podand ligand based on a tris(pyrazolyl)borate core, J CHEM S DA, (9), 2001, pp. 1389-1391
Citations number
33
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
14727773 → ACNP
Issue
9
Year of publication
2001
Pages
1389 - 1391
Database
ISI
SICI code
1472-7773(2001):9<1389:ACCHPL>2.0.ZU;2-F
Abstract
A hexadentate podand ligand having C-3 symmetry has been prepared, consisti ng of a tris(pyrazolyl)borate core bearing pinene-functionalised 2-pyridyl units attached to the C-3 position of each pyrazolyl ring such that each ar m is a chiral bidentate chelate; complexes with Tl(I) and Tb(III) have been prepared and structurally characterised.