The structural properties of the LaxSm1-xFeO3 trimetallic orthoferrites are
described on the basis of a Rietveld analysis of X-ray diffraction pattern
. Ultrafine powders of these oxides are prepared by the thermal decompositi
on at low temperatures of the corresponding hexacyanoncomplexes. Single-pha
se compounds are obtained. Their structural parameters can be tuned by prop
erly changing the Sm/La stoichiometric ratio. (C) 2001 Elsevier Science Ltd
. All rights reserved.