A hypothetical mechanism of carbon black formation based on molecular ballistic deposition

Citation
G. Heinrich et M. Kluppel, A hypothetical mechanism of carbon black formation based on molecular ballistic deposition, KAUT GUM KU, 54(4), 2001, pp. 159-165
Citations number
33
Categorie Soggetti
Material Science & Engineering
Journal title
KAUTSCHUK GUMMI KUNSTSTOFFE
ISSN journal
09483276 → ACNP
Volume
54
Issue
4
Year of publication
2001
Pages
159 - 165
Database
ISI
SICI code
0948-3276(200104)54:4<159:AHMOCB>2.0.ZU;2-D
Abstract
Motivated by recent experimental investigations of carbon black surface rou ghness and several new results emphasising the role of fullerene like precu rsor structures in carbon black formation, a first attempt for modelling th e nucleation and surface growth mechanisms during furnace black processing is presented, It is shown that the experimentally detected universal surfac e morphology independent of grade number can be explained on the one side b y numerical simulations of molecular ballistic deposition models and on the other side by the anisotropic KPZ equation, A particular solution of this equation, i.e. a circular shaped and pyramidal layered Toom interface, comp ares fairly well to the morphology obtained from TEM images of carbon black on nanoscopic length scales.