G. Heinrich et M. Kluppel, A hypothetical mechanism of carbon black formation based on molecular ballistic deposition, KAUT GUM KU, 54(4), 2001, pp. 159-165
Motivated by recent experimental investigations of carbon black surface rou
ghness and several new results emphasising the role of fullerene like precu
rsor structures in carbon black formation, a first attempt for modelling th
e nucleation and surface growth mechanisms during furnace black processing
is presented, It is shown that the experimentally detected universal surfac
e morphology independent of grade number can be explained on the one side b
y numerical simulations of molecular ballistic deposition models and on the
other side by the anisotropic KPZ equation, A particular solution of this
equation, i.e. a circular shaped and pyramidal layered Toom interface, comp
ares fairly well to the morphology obtained from TEM images of carbon black
on nanoscopic length scales.