Wh. Waddell et al., Improved tread compound wet/winter traction using brominated isobutylene-co-para-methylstyrene, KAUT GUM KU, 54(4), 2001, pp. 181-187
Use of brominated isobutylene-co-para-methylstyrene (BIMS) improves the lab
oratory dynamic properties predictive of wet and winter traction of formula
tions modeling all-season, winter and high-traction passenger tire treads.
Blends of BIMS with cis-polybutadiene, natural rubber, and solution-polymer
ized styrene-butadiene rubbers having varying microstructures were studied
in silica-filled compounds. Selective substitution of the BIMS elastomer wa
s made in order to evaluate the impact on abrasion resistance, and temperat
ure-dependent tangent delta values. Use of BIMS requires adjustments to the
curative system. By reducing both sulfur and accelerator(s) levels, compou
nd cure and mechanical properties can be maintained. The level of silane co
upling agent can also be reduced when using the BIMS elastomer.