We relate the strong enhancement of the Er3+ emission in amorphous + nanocr
ystalline GaN thin films alter annealing at 750 degreesC with changes in th
e microstructure and respective changes in the electronic system. We use hi
gh, resolution transmission electron microscopy (HRTEM), photothermal defle
ction spectroscopy and photoluminescence excitation measurements before and
after annealing. The main results concern distinct resonant absorption ban
ds of the Er3+ ions superimposed on a broad background absorption from the
amorphous matrix and very marked Stark splitting of the F-4(9 2) absorption
peak after optimal annealing. (C) 2001 Elsevier Science B.V. All rights re
served.