Quantum effects in the structure of liquid benzene at room temperature

Citation
Cj. Benmore et al., Quantum effects in the structure of liquid benzene at room temperature, MOLEC PHYS, 99(10), 2001, pp. 787-794
Citations number
23
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR PHYSICS
ISSN journal
00268976 → ACNP
Volume
99
Issue
10
Year of publication
2001
Pages
787 - 794
Database
ISI
SICI code
0026-8976(200105)99:10<787:QEITSO>2.0.ZU;2-1
Abstract
Structural differences between liquid light (protonated) benzene and heavy (deuterated) benzene at room temperature have been measured using high ener gy electromagnetic radiation scattering techniques. Intra- and intermolecul ar effects have been examined, and the main quantum contribution is shown t o be intramolecular. This is in contrast to the quantum-effects measured in liquid water at room temperature, which are primarily intermolecular.