CHIRAL PALLADIUM COMPLEX-CATALYZED SYNTHESIS OF OPTICALLY-ACTIVE VINYLCHROMAN

Authors
MIZUGUCHI E ACHIWA K
Citation
E. Mizuguchi et K. Achiwa, CHIRAL PALLADIUM COMPLEX-CATALYZED SYNTHESIS OF OPTICALLY-ACTIVE VINYLCHROMAN, Chemical and Pharmaceutical Bulletin, 45(7), 1997, pp. 1209-1211
Citations number
14
Categorie Soggetti
Pharmacology & Pharmacy",Chemistry
Journal title
Chemical and Pharmaceutical Bulletin → ACNP
ISSN journal
00092363
Volume
45
Issue
7
Year of publication
1997
Pages
1209 - 1211
Database
ISI
SICI code
0009-2363(1997)45:7<1209:CPCSOO>2.0.ZU;2-J
Abstract
Optically active vinylchroman (1) was synthesized from a corresponding allyl carbonate (2) by catalytic and asymmetric allylic substitution with palladium complexes of chiral bisphosphine Ligands, The reactivit y and selectivity of the various chiral bisphosphine-palladium complex es were investigated.