On the selective deprotection of cyanoethyl-protected tetrathiafulvalene thiolates

Authors
Nielsen, SB Nielsen, MB
Citation
Sb. Nielsen et Mb. Nielsen, On the selective deprotection of cyanoethyl-protected tetrathiafulvalene thiolates, NEW J CHEM, 25(5), 2001, pp. 769-771
Citations number
17
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
25
Issue
5
Year of publication
2001
Pages
769 - 771
Database
ISI
SICI code
1144-0546(2001)25:5<769:OTSDOC>2.0.ZU;2-P
Abstract
The selective deprotection protocol of cyanoethyl-protected tetrathiafulval ene thiolates is explained by DFT calculations on isomeric dithiolates; the minimum energy conformation of the 2,3-dithiolate (3) is non-planar and li es 34.6 kcal mol(-1) higher in energy than that of the 2,6-dithiolate (tran s-5).