Photoallylation and photoreduction of cyclohexylidenepropanedinitrile by use of allyltrimethylsilane via photoinduced electron transfer: Control of the product ratio depending on pK(a) values of additives

Authors
Hayamizu, T Ikeda, M Maeda, H Mizuno, K
Citation
T. Hayamizu et al., Photoallylation and photoreduction of cyclohexylidenepropanedinitrile by use of allyltrimethylsilane via photoinduced electron transfer: Control of the product ratio depending on pK(a) values of additives, ORG LETT, 3(9), 2001, pp. 1277-1280
Citations number
55
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
9
Year of publication
2001
Pages
1277 - 1280
Database
ISI
SICI code
1523-7060(20010503)3:9<1277:PAPOCB>2.0.ZU;2-X
Abstract
[GRAPHICS] Irradiation of an acetonitrile solution containing cyclohexylidenepropanedi nitrile (1) and allyltrimethylsilane (2) in the presence of phenanthrene af forded two kinds of allylated products (3, 4) and a reduction product (5). The product ratio of 3, 4, and 5 dramatically changed depending on the pK(a ) values of additives.