A convergent strategy for the synthesis of beta-carba-galacto-disaccharides

Authors
Cheng, XH Khan, N Kumaran, G Mootoo, DR
Citation
Xh. Cheng et al., A convergent strategy for the synthesis of beta-carba-galacto-disaccharides, ORG LETT, 3(9), 2001, pp. 1323-1325
Citations number
44
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
9
Year of publication
2001
Pages
1323 - 1325
Database
ISI
SICI code
1523-7060(20010503)3:9<1323:ACSFTS>2.0.ZU;2-G
Abstract
[GRAPHICS] A convergent strategy for the synthesis of beta -carba-galacto-disaccharide s is illustrated by the preparation of 1 and 4, from a central "glycone" co mponent 22, and the corresponding "aglycone" segments, monosaccharide alcoh ols, 23a or 23b, The key step is the formation of the carbasugar ring via a n oxocarbenium ion-enol ether cyclization.