cis-vinylphosphonates and 1,3-butadienylphosphonates by zirconation of 1-alkynylphosphonates

Authors
Quntar, AA Srebnik, M
Citation
Aa. Quntar et M. Srebnik, cis-vinylphosphonates and 1,3-butadienylphosphonates by zirconation of 1-alkynylphosphonates, ORG LETT, 3(9), 2001, pp. 1379-1381
Citations number
39
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
9
Year of publication
2001
Pages
1379 - 1381
Database
ISI
SICI code
1523-7060(20010503)3:9<1379:CA1BZO>2.0.ZU;2-7
Abstract
[GRAPHICS] Addition of "zirconocene" to 1-alkynylphosphonates gives three-membered zir conacylces that can be hydrolyzed to cis-vinylphosphonates or further react ed with alkynes/hydrolysis to give substituted (Z,E)- and (E,E)-1,3-butadie nylphosphonates.