Syntheses of platinum(IV) aryl dihydride complexes via arene C-H bond activation

Authors
Reinartz, S White, PS Brookhart, M Templeton, JL
Citation
S. Reinartz et al., Syntheses of platinum(IV) aryl dihydride complexes via arene C-H bond activation, ORGANOMETAL, 20(8), 2001, pp. 1709-1712
Citations number
41
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
8
Year of publication
2001
Pages
1709 - 1712
Database
ISI
SICI code
0276-7333(20010416)20:8<1709:SOPADC>2.0.ZU;2-X
Abstract
Tp ' PtMeH2 (1) reacts with substoichiometric amounts of B(C6F5)(3) in arom atic solvents to yield platinum(IV) aryl dihydride complexes via borane-ind uced reductive elimination of methane from I and subsequent C-H activation of the aromatic solvent.