The present work analyzes the oxidation kinetics of MA 956 and PM 2000 allo
ys at 900 and 1100 degreesC for exposure times up to 1000 hr. Special empha
sis was placed on a comparison of the alumina-scale integrity formed at 110
0 degreesC by means of electrochemical tests at room temperature, which hav
e been shown to be very reliable methods to detect the presence of microdef
ects within oxide scales. To check whether a preoxidation treatment makes t
hese materials corrosion resistant against aggressive fluids, an electrolyt
e containing chloride ions was chosen. The mass gain of MA 956 was found to
be slightly lower than that of PM 2000 up to 200 hr exposure at 1100 degre
esC and for the M whole exposure range at 900 degreesC. A subparabolic time
dependence (n=0.3) of the oxide growth rate was determined for both alloys
at both temperatures. On the other hand, the electrochemical-impenance spe
ctroscopy (EIS) and anodic-polarization tests performed on preoxidized allo
ys (1100 degreesC/100 hr) revealed goon room-temperature corrosion behavior
for both alloys, the corrosion resistance and polarization values being so
mewhat higher for preoxidized PM 2000. Consideration of these results and t
hose of both surface and cross-section examinations of the scale, the bette
r room-temperature corrosion behavior of preoxidized PM 2000 denotes the fo
rmation of a denser and mechanically more stable alumina scale containing a
lower number of microdefects. This could result from the higher aluminum c
ontent of this alloy and the lower density of chemical heterogeneities with
in the scale. The higher mass gain of PM 2000 could be related to the highe
r concentration of oxide nodules on top of the alumina scale, as deduced fr
om SEM examination.