We consider off-diagonal contributions to double sums over periodic orbits
that arise in semiclassical approximations for spectral statistics of class
ically chaotic quantum systems. We identify pairs of periodic orbits whose
actions are strongly correlated. For a class of systems with uniformly hype
rbolic dynamics, we demonstrate that these pairs of orbits give rise to a t
au (2) contribution to the spectral form factor K(tau) which agrees with ra
ndom matrix theory. Most interestingly, this contribution has its origin in
a next-to-leading-order behaviour of a classical distribution function for
long times.