Experimental study of the equation of state and the surface tension of water-soluble polymers: poly(ethylene glycol)-b-poly(propylene glycol)-b-poly(ethylene glycol) plus water at 298.15 K
A. Compostizo et al., Experimental study of the equation of state and the surface tension of water-soluble polymers: poly(ethylene glycol)-b-poly(propylene glycol)-b-poly(ethylene glycol) plus water at 298.15 K, PHYS CHEM P, 3(10), 2001, pp. 1861-1866
The equation of state of poly(ethylene glycol)-b-poly(propylene glycol)-b-p
oly(ethylene glycol) (PEG-PPG-PEG)+water has been measured in the sol phase
at 298.15 K and up to 40 MPa. For the sake of comparison two mixtures of (
PEG+PPG)+water, with the same PEG:PPG ratio as the copolymer, have been mea
sured. The differences found between the data of the copolymer and the blen
d solutions are well beyond the experimental precision, the compressibility
for the copolymer mixtures being larger than for the blend one. Contrary t
o previous non-aqueous mixtures, the aqueous ones present deviations with r
espect to the corresponding states equation proposed by the group of Sanche
z (I. C. Sanchez, J. Cho and W. J. Chen, Macromolecules, 1993, 26, 4234). T
he surface tension gamma results show that both PEG-PPG-PEG and PPG are sur
face active, leading to a strong decrease of gamma with respect to that of
water even for very low polymer concentrations. The behaviour of the spinod
al pressure of the system is discussed in terms of the compressibility and
the surface tension data.