The interaction of N,N '-diethyl-4,4 '-bipyridinium cation with hexacyanoferrate(II) anions in aqueous solution

Authors
Kostina, SA Golovaneva, IF Kotov, VY
Citation
Sa. Kostina et al., The interaction of N,N '-diethyl-4,4 '-bipyridinium cation with hexacyanoferrate(II) anions in aqueous solution, RUSS J IN C, 46(4), 2001, pp. 619-621
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
4
Year of publication
2001
Pages
619 - 621
Database
ISI
SICI code
0036-0236(200104)46:4<619:TION''>2.0.ZU;2-G
Abstract
The interaction of the hexacyanoferrate ion with the N,N ' -diethyl-4,4 ' - bipyridinium cation was studied spectrophotometrically. The background elec trolyte cation concentration has an effect on the charge-transfer band posi tions in the ion pairs. The stability constant and molar absorptivity of th e ion pair and the rate constant of electron transfer between the ions were calculated.