A solid-phase version of the palladium-catalyzed carbonyl allylation by allylic alcohols with SnCl2

Authors
Carde, L Llebaria, A Delgado, A
Citation
L. Carde et al., A solid-phase version of the palladium-catalyzed carbonyl allylation by allylic alcohols with SnCl2, TETRAHEDR L, 42(19), 2001, pp. 3299-3302
Citations number
9
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
19
Year of publication
2001
Pages
3299 - 3302
Database
ISI
SICI code
0040-4039(20010507)42:19<3299:ASVOTP>2.0.ZU;2-5
Abstract
A solid-phase version of the palladium-catalyzed carbonyl allylation of ald ehydes by allylic alcohols is described. Preliminary studies have been carr ied out with resin bound aldehydes 1a-c and different allylic alcohols. Sol vent effects as well as the regio- and diastereoselectivity of our solid-ph ase conditions are compared with solution-phase protocols. (C) 2001 Elsevie r Science Ltd. All rights reserved.