Efficient deep-blue electroluminescence (EL) is obtained via end-capping po
lyfluorene (PF) homopolymers with hole-transporting moieties (HTMs). Strong
evidence that the observed improvement in device performance is related to
the end-capper moieties comes from the comparison of two different end-cap
pers. The HTM does not disturb the liquid-crystal properties of the PF poly
mer. Using doped polyimide alignment layers. polarized light-emitting diode
s (LEDs) with a polarization ratio in excess of twenty at an efficiency of
0.25 cd/A could be realized.