Zh. Wang et al., Excess enthalpies of the ternary mixtures: ethyl tert-butylether plus n-heptane plus (n-decane or n-dodecane) at 298.15 K, CAN J CHEM, 79(4), 2001, pp. 388-393
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
Excess molar enthalpies, measured at 298.15 K in a flow microcalorimiter, a
re reported for the two ternary systems, ethyl tert-butylether + n-heptane
+ n-decane and ethyl tert-butylether + n-heptane + n-dodecane. Smooth repre
sentations of the results were used to construct constant enthalpy contours
on Roozeboom diagrams. It is shown that useful estimates of the ternary en
thalpies can be obtained from the Liebermann-Fried model using only the phy
sical properties of the components and their binary mixtures.