Chelated fluoroboron cations. III. Spectroscopic evidence for ring size and steric limitations to chelate formation by amine chelating donors

Authors
Hartman, JS Shoemaker, JAW
Citation
Js. Hartman et Jaw. Shoemaker, Chelated fluoroboron cations. III. Spectroscopic evidence for ring size and steric limitations to chelate formation by amine chelating donors, CAN J CHEM, 79(4), 2001, pp. 426-436
Citations number
38
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
ISSN journal
00084042 → ACNP
Volume
79
Issue
4
Year of publication
2001
Pages
426 - 436
Database
ISI
SICI code
0008-4042(200104)79:4<426:CFCISE>2.0.ZU;2-E
Abstract
Factors affecting the ability of potentially chelating amine ligands to for m chelated fluoroboron cations are explored by F-19 and B-11 NMR spectrosco py and fast atom bombardment mass spectrometry (FAB-MS). Five-membered chel ate rings form much more readily than six-membered. Some potentially chelat ing ligands give rise to additional fluoroboron species by various redistri bution and decomposition reactions.