The influences of the gas rate dissolution and mass-transfer limitation atthe interfaces on selectivity of gas-liquid processes in stirred reactors with a suspended catalyst
Ef. Stefoglo et al., The influences of the gas rate dissolution and mass-transfer limitation atthe interfaces on selectivity of gas-liquid processes in stirred reactors with a suspended catalyst, CATAL TODAY, 66(2-4), 2001, pp. 397-402
A complex mathematical model accounting for the hydrogen dissolution proces
s in suspensions and mass-transfer steps at the Liquid-solid interface for
the gas and Liquid components is given. The calculated data according to th
e model for the reaction A --> B --> C shows, that the yield of an intermed
iate product B is very much affected by the relation of the gas component m
ass-transfer coefficient on the gas-liquid interface to that on the liquid-
solid one. The hydrogenation of chlornitroaromatic compounds was analysed.
The kinetics of the catalytic reduction of p-chlornitrobenzene to p-chloran
iline via corresponding arylhydroxilamine on the Ir/C catalyst experimental
ly in a batch reactor has been studied. In this process the first reactions
depend on the hydrogen concentration but the second ones are not dependent
- this is a disproportion of the intermediate product to the final product
- amine. (C) 2001 Elsevier Science B.V. All rights reserved.