Solid state supramolecular assemblies of charged supermolecules (Na[2.2.2]cryptate)(+) and anionic carboranes with host cyclotriveratrylene

Authors
Hardie, MJ Raston, CL
Citation
Mj. Hardie et Cl. Raston, Solid state supramolecular assemblies of charged supermolecules (Na[2.2.2]cryptate)(+) and anionic carboranes with host cyclotriveratrylene, CHEM COMMUN, (10), 2001, pp. 905-906
Citations number
22
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
10
Year of publication
2001
Pages
905 - 906
Database
ISI
SICI code
1359-7345(2001):10<905:SSSAOC>2.0.ZU;2-5
Abstract
The complex {(Na[2.2.2]cryptate)[CTV][Co(C2B9H11)(2)]}(2)- (MeCN) (CTV = cy clotriveratrylene) features (Na[2.2.2]cryptate)(+)boolean AND CTV interplay as well as a closely packed chain of [Co(C2B9H11)(2)](-) counter-anions ex hibiting dihydrogen bonding, and a similar cation-CTV assembly is found in (Na[2.2.2]cryptate)[CTV](CHCl3)(3)[CB11H12].