5-Exo-dig, 5-exo-trig cascade radical cyclisation on sugar-furanose templates: entry to angularly fused oxa- and dioxa-triquinane skeletons

Authors
Gurjar, MK Ravindranadh, SV Kumar, P
Citation
Mk. Gurjar et al., 5-Exo-dig, 5-exo-trig cascade radical cyclisation on sugar-furanose templates: entry to angularly fused oxa- and dioxa-triquinane skeletons, CHEM COMMUN, (10), 2001, pp. 917-918
Citations number
36
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
10
Year of publication
2001
Pages
917 - 918
Database
ISI
SICI code
1359-7345(2001):10<917:55CRCO>2.0.ZU;2-X
Abstract
Serial radical cyclisation on sugar-furanose templates to create angularly fused oxa- and dioxa-triquinane skeletons has been described, the salient f eature of this approach being to incipiently generate a tertiary radical fr om cyclopropylmethyl bromide with simultaneous release of allyl group and t o subsequently incorporate it in the triquinane system.