Infrared spectroscopy of aniline (C6H5NH2) and its cation in a cryogenic argon matrix

Authors
Gee, C Douin, S Crepin, C Brechignac, P
Citation
C. Gee et al., Infrared spectroscopy of aniline (C6H5NH2) and its cation in a cryogenic argon matrix, CHEM P LETT, 338(2-3), 2001, pp. 130-136
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
338
Issue
2-3
Year of publication
2001
Pages
130 - 136
Database
ISI
SICI code
0009-2614(20010420)338:2-3<130:ISOA(A>2.0.ZU;2-D
Abstract
Infrared absorption spectra of aniline, trapped in a low-temperature 5 K ar gon matrix, have been obtained in the spectral region from 500 to 4000 cm(- 1). The aniline cation C6H7N+, was formed inside the matrix by UV laser irr adiation. We report the first IR absorption spectroscopy of this cation in an argon matrix: five fundamental vibrational bands were observed. (C) 2001 Elsevier Science B.V. All rights reserved.