Recycling of metals and plastics from wastes is one of the major applicatio
ns of the electrostatic separation technologies. The paper analyses the mul
titude of factors that affect the efficiency of this technique, to establis
h design principles and formulate operation recommendations. The theoretica
l analysis of corona and induction charging of, respectively, insulating an
d conducting particles allows a crude evaluation of the role of the various
factors involved, including the electric field strength E-0, and the curre
nt density J in the active zone of the separator. A first set of experiment
s has been carried out for estimating E-0, J and the charging time constant
tau, based on the measurement of the current-voltage characteristic of a s
tandard electrode arrangement. A second set of experiments consisted of thr
ee series of separation tests performed on samples of millimetre-sized gran
ulated electric wire scrap (62.5% copper, 37.5% PVC). By using a combined c
orona-electrostatic field and a three-stage separation scheme? a PVC concen
trate containing less than 0.04% copper (recovery: 92.2%) and a copper prod
uct with less than 0.1% PVC (recovery: 90.8%) were obtained. Design and ope
ration recommendations were formulated regarding the optimum electrode arra
ngement, high-voltage level, roll speed and feed rate for typical industria
l applications.