Kc. Tee et al., Effects of deliberate copper contamination from the plating solution on the electrical characteristics of MOSFETs, IEEE SEMIC, 14(2), 2001, pp. 170-172
N-channel and p-channel metal-oxide-semiconductor (MOS) transistors of vari
ous (W/L) ratios down to 0.24-mum channel length have been used to investig
ate the effects of deliberate backside copper (Cu) contamination on the MOS
field-effect transistor (MOSFET) electrical parameters. The backside of th
e wafer was flooded with copper sulphate (CuSO4) solution and air-dried. Hi
gh-temperature annealing was carried out to drive Cu into silicon. It was d
iscovered that the backside Cu contamination did not result in any undesira
ble effects on the MOS device performance. The MOS device parameters such a
s threshold voltage V-T0, transconductance G(m), drain saturation current I
-DSAT, off-current I-off, and junction leakage current for n(+)/p and p(+)/
n. diodes displayed no significant degradation, even after 5 h of annealing
at 400 degreesC in nitrogen ambient. Secondary ion mass spectroscopy data
shows that Cu diffused into silicon only over a short distance, leading to
little or no degradation of MOSFETs and junction diodes.