Organotitanoxanes [C5Me5TiMe2](2)(mu-O)) and [(C5Me5)(4)Ti4Me2](mu-O)(5): Synthesis and crystal structures

Authors
Varkey, SP Schormann, M Pape, T Roesky, HW Noltemeyer, M Herbst-Irmer, R Schmidt, HG
Citation
Sp. Varkey et al., Organotitanoxanes [C5Me5TiMe2](2)(mu-O)) and [(C5Me5)(4)Ti4Me2](mu-O)(5): Synthesis and crystal structures, INORG CHEM, 40(10), 2001, pp. 2427
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
10
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010507)40:10<2427:O[A[S>2.0.ZU;2-F
Abstract
Hydrolytic studies on C5Me5TiCl3 and C5Me5TiMe3 resulted in the isolation o f [(C5Me5)(4)Ti4Cl2](mu -O)(5) (2a) and [C5Me5TiMe2](2)(mu -O) (1). Compoun d 2a further reacted with Me3SnF to yield [(CsMe5)(4)Ti4F2](mu -O)(5) (2b). Furthermore, the reactivity of 2b toward AlMe3 has been investigated and r esults in the formation of [(C5Me5)(4)Ti4Me2](mu -O)(5) (2c). Crystal struc tures of I and 2c have been established.