Synthesis, structure, and catalytic reactivity of N,N,S- and O,N,S-tridentate oxorhenium(V) complexes

Authors
Zhang, CG Guzei, IA Espenson, JH
Citation
Cg. Zhang et al., Synthesis, structure, and catalytic reactivity of N,N,S- and O,N,S-tridentate oxorhenium(V) complexes, INORG CHEM, 40(10), 2001, pp. 2437
Citations number
9
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
10
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010507)40:10<2437:SSACRO>2.0.ZU;2-L
Abstract
Three new oxorhenium(V) catalysts have been synthesized; the one whose stru ctural formula is shown was characterized crystallographically. These compo unds catalyze oxygen atom transfer from pyridine N-oxide to tris(trimethylp henyl)phosphine in chloroform at room temperature.