Polymerization of chlorofluorocarbon-22 and acetonitrile

Citation
Gq. Shi et al., Polymerization of chlorofluorocarbon-22 and acetonitrile, J APPL POLY, 81(1), 2001, pp. 116-120
Citations number
11
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
JOURNAL OF APPLIED POLYMER SCIENCE
ISSN journal
00218995 → ACNP
Volume
81
Issue
1
Year of publication
2001
Pages
116 - 120
Database
ISI
SICI code
0021-8995(20010705)81:1<116:POCAA>2.0.ZU;2-O
Abstract
Chlorofluorocarbon-22 (HCCIF2) gas call react with acetonitrile to form a h alogen-free carbon-based polymer when solid potassium hydroxide particles a re present. The reaction can be carried out under nor mal pressure and at r oom temperature. The polymer is powdery and amorphous. The structure of the polymer has been studied by elemental analysis, Fourier transform Iii, Ram an, and mass spectroscopies. The results demonstrate that the polymer has a carbonic backbone. (C) 2001 John Wiley & Sons. Inc. J Appl Polym Sci 81: 1 16-120, 2001.