The mechanisms of brittle-to-ductile transition of fracture in intrinsicall
y brittle crystalline solids such as structural steel have been of great te
chnological interest for a long time. While much useful phenomenology on th
is important bifurcation behavior has evolved through material testing and
alloy development throughout the period following the large scale fractures
in Liberty ships during and after World War II, fundamental mechanistic un
derstanding has been lacking until recent times. Over the past decade or so
, a renewed level of interest has resulted in a number of fundamental studi
es of both experimental nature and modeling of crack-tip response which dem
onstrated a remarkable connection of atomic level processes at tips of clea
vage cracks and the macroscopic fracture transitions. These mechanistic con
nections have not only gone a long way in providing basic rationale for som
e of the successful empirical practices in alloy design and microstructure
control, but clear the way for further advances based on basic atomic level
processes governing crystal plasticity. Here we give an overview of some r
ecent developments in this area emanating from our own researches.