M. Fukuhara et A. Sampei, Stress-induced pyroelectric properties of devitrified fused quartz in elevated temperature, J MAT S-M E, 12(2), 2001, pp. 131-135
We observed a cyclic oscillation of the electromotive force (emf) for a dev
itrified fused quartz in the specific temperature region between 917 and 14
29 K and frequency range between 2 and 7.5 MHz. The oscillation is composed
of low temperature-small and high temperature-large elements. These could
be due to the tertiary and the secondary pyroelectric effects, respectively
, derived from a lone-pair electron configuration of O2- at the tetrahedron
corners of the beta (2)-tridymite phase. The ultrasonic frequency causes a
cyclic change of emf difference, based on a stress-induced pyroelectricity
. (C) 2001 Kluwer Academic Publishers.